Sting Scorpion Death Drop

This move is interesting because of the unique setup, which is a headlock, but the opponents face is towards the sky. Thanks to this unique positioning, crowds can immediately recognize the move and go nuts, all while Sting stares back at them, waiting just slightly before driving the back of his foes head to the mat.
A lightning quick setup allows Sting to get the jump on wrestlers, which was necessary in WCW, when he had to take on the 108 members of the n.W.o. Okay, maybe not 108, but he was usually a lone wolf and had to strike quickly to survive the show.